Chemistry Chapter 4 Vocabulary

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HUND'S RULE

orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron, and all electrons in singly occupied orbitals must have the same spin state (electrons will distribute themselves evenly if in the same orbital)

PAULI EXCLUSION PRINCIPLE

no two electrons in the same atom can have the same set of four quantum numbers (no two electrons can have the same spin)

THE AUFBAU PRINCIPLE

an electron occupies the lowest-energy orbital that can receive it (electrons will go into orbitals of lowest energy first)

QUANTUM NUMBERS

specify the properties of atomic orbitals and the properties of electrons in orbitals (s, p, d, f)

ELECTRON CONFIGURATION

the arrangement of electrons in an atom

ORBITAL NOTATION

an unoccupied orbital is represented by a line, with the orbital’s name written underneath the line

NOBLE GAS NOTATION

take the electron configuration of the noble gas closest to the given element and then write what remains

AMPLITUDE

wave height

FREQUENCY

waves per second

WAVELENGTH

distance between waves

CREST

top of a wave

TROUGH

bottom of a wave

HEISENBERG'S UNCERTAINTY PRINCIPLE

states that it is impossible to determine simultaneously both the position and velocity of an electron or any other particle

EXCITED STATE

A state in which an atom has a higher potential energy than it has in its ground state

GROUND STATE

The lowest energy state of an atom

QUANTUM THEORY

describes mathematically the wave properties of electrons and other very small particles

PHOTOELECTRIC EFFECT

refers to the emission of electrons from a metal when light shines on the metal

PHOTON

particle of electromagnetic radiation having zero mass and carrying a quantum of energy

ELECTROMAGNETIC RADIATION

a form of energy that exhibits wavelike behavior as it travels through space


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